机构：[1]State Key Laboratory of Structural Chemistry, and Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, Fuzhou 350100, China[2]Orthopedics Department, Guangdong Provincial Hospital of Traditional Chinese Medicine, The Second Affiliated Hospital of Guangzhou University of Chinese Medicine, Guangzhou 510120, China广东省中医院
Developing a general method affording optically pure fully substituted carbon molecules bearing various fluorinated groups is highly important but very challenging. Here we show that using secondary OH as a kinetic resolution auxiliary group, a series of previously unavailable fluorinated fully substituted carbon molecules can be obtained with excellent enantioselectivities, thus providing an alternative complementary method that provides solutions to the limitations confronted by the known methods.
基金：
NSFC (22071242 and
21871260), the Strategic Priority Research Program of the
Chinese Academy of Sciences (XDB20000000), Fujian Natural
Science Foundation (2018J05035), and the Fujian Institute of
Research on the Structure of Matter, Chinese Academy of
Sciences.
第一作者机构：[1]State Key Laboratory of Structural Chemistry, and Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, Fuzhou 350100, China
推荐引用方式(GB/T 7714)：
Zehra Syeda Tazeen,Lan Shouang,Zhang Hao,et al.Access to enantioenriched molecules with diverse fluorinated tetrasubstituted stereocenters using hydroxy as a kinetic resolution auxiliary group[J].ORGANIC CHEMISTRY FRONTIERS.2022,9(4):1040-1047.doi:10.1039/d1qo01493e.
APA：
Zehra, Syeda Tazeen,Lan, Shouang,Zhang, Hao,Liu, Jinggong,Yang, Shuang&Fang, Xinqiang.(2022).Access to enantioenriched molecules with diverse fluorinated tetrasubstituted stereocenters using hydroxy as a kinetic resolution auxiliary group.ORGANIC CHEMISTRY FRONTIERS,9,(4)
MLA：
Zehra, Syeda Tazeen,et al."Access to enantioenriched molecules with diverse fluorinated tetrasubstituted stereocenters using hydroxy as a kinetic resolution auxiliary group".ORGANIC CHEMISTRY FRONTIERS 9..4(2022):1040-1047
化学