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Copper-Catalyzed Cross-Coupling of Benzylic Bromides with Arylboronic Acids: Synthesis of Diarylalkanes and Preliminary Antifungal Evaluation Against Magnaporthe Grisea

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收录情况： ◇ SCIE

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机构： [1]Department of Applied Chemistry College of Materials and Energy South China Agricultural University Guangzhou, 510642 (P. R. China) [2]Key Laboratory of Natural Pesticide & Chemical Biology Ministry of Education South China Agricultural University Guangzhou, 510642 (P. R. China) [3]Orthopedics Department Guangdong Provincial Hospital of Traditional Chinese Medicine The Second Affiliated Hospital of Guangzhou University of Chinese Medicine Guangzhou, 510120 (P. R. China)

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关键词： copper cross-coupling homogeneous catalysis radicals antibacterial evaluation

摘要：

Reported herein is the practical synthesis of 1,1-diarylalkanes motifs via copper-catalyzed cross-coupling reaction of benzylic bromides with arylboronic acids under mild conditions. The protocols show broad scope and good functional group tolerance, and are also applicable to complex natural products. Mechanistic study indicates a radical mechanism. Moreover, preliminary antibacterial evaluation against Magnaporthe grisea is also described for the first time.

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出版当年[2019]版：

大类 | 3 区化学

小类 | 3 区有机化学

最新[2025]版：

大类 | 3 区化学

小类 | 3 区有机化学

JCR分区：

出版当年[2018]版：

Q2 CHEMISTRY, ORGANIC

最新[2023]版：

Q1 CHEMISTRY, ORGANIC

影响因子： 2.8 最新[2023版] 2.8 最新五年平均 2.496 出版当年[2018版] 2.503 出版当年五年平均 2.496 出版前一年[2017版] 3.13 出版后一年[2019版]

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第一作者机构： [1]Department of Applied Chemistry College of Materials and Energy South China Agricultural University Guangzhou, 510642 (P. R. China)

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通讯作者：

通讯机构： [1]Department of Applied Chemistry College of Materials and Energy South China Agricultural University Guangzhou, 510642 (P. R. China) [2]Key Laboratory of Natural Pesticide & Chemical Biology Ministry of Education South China Agricultural University Guangzhou, 510642 (P. R. China)

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